戊基磷酸二戊酯萃取色层分离-电感耦合等离子体质谱法测定铀产品中9种杂质元素     

朱留超  王同兴  赵永刚  徐常昆  赵立飞  姜小燕  赵兴红 《岩矿测试》2015,34(4):414-419

铀产品中杂质元素的含量测定在核法证学溯源分析或燃料元件厂质量检验中具有重要应用价值,保证测量的准确度主要在于控制流程空白、提高杂质元素的回收率。本文建立了戊基磷酸二戊酯(UTEVA)树脂快速分离铀与杂质元素、电感耦合等离子体质谱法(ICP-MS)测定杂质元素含量的系统流程。结果表明,UTEVA树脂对铀的吸附能力强,铀样品取样量为16.43 mg时,全流程对铀的去污因子大于3×105,9种杂质元素(锰钼镍铜铬铝钛钒镉)的回收率为95.1%~105.1%,国家标准物质GBW04205中杂质元素的分析结果与参考值在不确定度(k=2)范围内一致。本工作建立的分离流程对铀的去污效果好,特别适用于样品量少的情况下铀中杂质元素的分析,为核法证分析最终的归因溯源或燃料质量检验提供了技术支持。  相似文献   

酸溶-电感耦合等离子发射光谱法测定密西西比型铅锌矿床矿石中的铅   总被引：1，自引：1，他引：0  

卢彦  冯勇  李刚  刘卫 《岩矿测试》2015,34(4):442-447

密西西比型(MVT)铅锌矿床的主要矿物有方铅石、闪锌矿,常伴生有重晶石、萤石等矿物,使得MVT型矿石在酸处理过程中易生成不溶于水和酸的硫酸铅钡复盐,故而检测矿样中铅的含量偏低。本文建立了采用盐酸-硝酸-氢氟酸体系酸溶分解MVT型矿石,电感耦合等离子体发射光谱法(ICP-OES)测定铅含量的分析方法。实验比较了盐酸-硝酸-氢氟酸、盐酸-硝酸-氢氟酸-高氯酸、盐酸-硝酸-硫酸三种酸溶体系的溶样效果,并通过X射线衍射论证了方法的可行性。结果表明,盐酸-硝酸-氢氟酸体系克服了复盐硫酸铅钡和硫酸铅沉淀的生成,适量的氢氟酸促进了Pb SO4的溶解,X射线衍射表征也表明此种酸溶体系的沉淀中不含有Pb SO4,可更彻底地分解MVT型矿石。本方法精密度(RSD)为0.3%~0.6%,实际样品的加标回收率为96.0%~99.2%,铅的最佳检测范围为0.01%~20.0%。  相似文献   

电感耦合等离子体质谱法测定灌木枝叶中微量元素的样品预处理方法研究   总被引：1，自引：1，他引：0  

林伟龙  王正海  王娟  蒋丽怡  范朝焰 《岩矿测试》2015,34(4):430-435

利用电感耦合等离子体质谱法(ICP-MS)测定植物样品中微量元素的关键技术是消除植物样品的有机基体效应,本文通过预处理方法中的酸消解体系、称样量和消解方式消除其影响。以国家标准物质灌木枝叶组合样(GBW07603)为材料进行研究,对比分析了硝酸-过氧化氢、硝酸-氢氟酸、硝酸-氢氟酸-过氧化氢3种酸溶体系的消解效果,以确定最佳酸溶体系,进而定量研究2种称样量(50 mg和100 mg)和3种消解方式(密封高压二次消解、密封高压一次消解、微波消解)的消解效果,并以In作为内标采用ICP-MS测定微量元素含量。结果表明:硝酸-氢氟酸-过氧化氢酸溶体系的消解效果最好;50 mg的测定值更接近于参考值;微波消解法的测定值明显偏低,而密封高压二次消解法是灌木枝叶样品预处理的有效方法。  相似文献   

赣东北朱溪铜钨矿区花岗闪长斑岩LA-ICP-MS锆石U-Pb定年及地质意义   总被引：6，自引：0，他引：6  

万浩章  刘战庆  刘善宝  陈毓川  王成辉  陈国华  梁力杰  李赛赛  张树德  刘小林 《岩矿测试》2015,34(4):494-502

赣东北朱溪超大型铜钨矿位于江南古岛弧带塔前—赋春成矿带中段,该矿床的发现可进一步验证"南钨北扩"观点并对"南钨北铜"格局提出挑战,但前人对与朱溪铜钨矿成矿作用有关的花岗岩缺少精确的年代学研究,导致对其地球动力学背景理解不够深入。本研究通过详细的野外调查、岩心编录和岩矿鉴定,并利用激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)锆石U-Pb法对朱溪铜钨矿区侵入元古代双桥山岩群中的铜矿化花岗闪长斑岩进行测年,获得了锆石206Pb/238U加权平均年龄为847.2±9.4 Ma(MSWD=0.111),代表了其侵位结晶的年龄,属新元古代。分析认为:朱溪铜钨矿区铜矿化花岗闪长斑岩是新元古代早期华南古洋壳俯冲消减及扬子陆块与华夏陆块发生碰撞作用下的岩浆产物,这次岩浆活动与区域上塔前—赋春成矿带成矿作用关系密切,并为钦—杭成矿带提供了成矿物质基础。本次对其成岩年龄的限定,为研究朱溪超大型铜钨矿矿床提供了新证据。  相似文献   

激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展   总被引：9，自引：5，他引：4  

吴石头  王亚平  许春雪 《岩矿测试》2015,34(5):503-511

激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是目前地球科学分析领域的重要技术手段,元素微区分析标准物质研制是该分析技术发展的重要方向。本文对当前LA-ICP-MS元素微区分析标准物质的种类、元素分布以及应用上的优缺点和标准物质的制备方法进行了评述。现有的有证标准物质数量不多、种类不齐全,部分元素浓度较低,定值不确定度较大,应用上受到较大的局限性;研制标准也不成熟,均匀性检验方面尚未有统一的方法。本文参照岩石粉末标准物质均匀性检验方法提出了两步均匀性检验法,同时指出在标准物质种类方面,铂族元素及Au元素浓度适当、Pb-S等不同硫化物基体标准物质,以及化学成分不同的碳酸岩和磷酸岩基体标准物质是当前的迫切需求;在标准物质研制技术方面,纳米岩石粉末压片技术的研发、原位微区分析标准物质(固体)均匀性检验判别标准研究是亟待解决的问题。  相似文献   

对X射线荧光光谱分析检出限公式的认识     

马旻  刘江斌 《甘肃地质》2011,(2):73-75

对X射线荧光光谱分析检出限问题进行了探讨,通过实验指出行标DZ/T 130-2006有关检出限计算公式的不足在于对测量时间的过分依赖,使检出限这一重要参数失去实际意义,需要重新科学定义。  相似文献   

Coupled discrete element and finite volume solution of two classical soil mechanics problems     

Feng Chen  Eric. C. Drumm  Georges Guiochon 《Computers and Geotechnics》2011

One dimensional solutions for the classic critical upward seepage gradient/quick condition and the time rate of consolidation problems are obtained using coupled routines for the finite volume method (FVM) and discrete element method (DEM), and the results compared with the analytical solutions. The two phase flow in a system composed of fluid and solid is simulated with the fluid phase modeled by solving the averaged Navier–Stokes equation using the FVM and the solid phase is modeled using the DEM. A framework is described for the coupling of two open source computer codes: YADE-OpenDEM for the discrete element method and OpenFOAM for the computational fluid dynamics. The particle–fluid interaction is quantified using a semi-empirical relationship proposed by Ergun [12]. The two classical verification problems are used to explore issues encountered when using coupled flow DEM codes, namely, the appropriate time step size for both the fluid and mechanical solution processes, the choice of the viscous damping coefficient, and the number of solid particles per finite fluid volume.  相似文献   

Interannual variability of the sea surface salinity and its related freshwater flux in the tropical Pacific: A comparison of CMIP5 and CMIP6          下载免费PDF全文

Hai Zhi  Yu Huang  Pengfei Lin  Shiwei Shi  Meng Dong 《大气和海洋科学快报》2022,15(4):100190

This paper assesses the interannual variabilities of simulated sea surface salinity (SSS) and freshwater flux (FWF) in the tropical Pacific from phases 5 and 6 of the Coupled Model Intercomparison Project (CMIP5 and CMIP6). The authors focus on comparing the simulated SSS and FWF responses to El Niño–Southern Oscillation (ENSO) from two generations of models developed by the same group. The results show that CMIP5 and CMIP6 models can perform well in simulating the spatial distributions of the SSS and FWF responses associated with ENSO, as well as their relationship. It is found that most CMIP6 models have improved in simulating the geographical distribution of the SSS and FWF interannual variability in the tropical Pacific compared to CMIP5 models. In particular, CMIP6 models have corrected the underestimation of the spatial relationship of the FWF and SSS variability with ENSO in the central-western Pacific. In addition, CMIP6 models outperform CMIP5 models in simulating the FWF interannual variability (spatial distribution and intensity) in the tropical Pacific. However, as a whole, CMIP6 models do not show improved skill scores for SSS interannual variability, which is due to their overestimation of the intensity in some models. Large uncertainties exist in simulating the interannual variability of SSS among CMIP5 and CMIP6 models and some improvements with respect to physical processes are needed.摘要通过比较CMIP5和CMIP6来自同一个单位两代模式模拟, 表明CMIP5和CMIP6均能较好地模拟出热带太平洋的海表盐度 (SSS) 和淡水通量 (FWF) 对ENSO响应的分布及其响应间的关系. 与CMIP5模式相比, 大部份CMIP6模式模拟的SSS和FWF年际变化分布均呈现改进, 特别是纠正了较低的中西太平洋SSS和FWF变化的空间关系. 但是, 整体上, CMIP6模式模拟的SSS年际变化技巧没有提高, 与SSS年际变率的强度被高估有关. CMIP5和CMIP6模式模拟SSS的年际变化还存在较大的不确定性, 在物理方面需要改进.  相似文献   

CMIP6与CMIP5对历史大气层顶和地表辐射收支模拟的时空对比     

万梓文  王伟  吕恒  仇培宇  李雨竹  卢阳 《气候变化研究进展》2022,18(4):468-481

基于云和地球辐射能量系统观测数据集（CERES),对比分析了耦合模式比较计划第五（CMIP5）和第六阶段（CMIP6）模拟的历史大气层顶和地表辐射收支的年际变化和空间分布,明确了多模式间不确定性大的关键区域。结果表明：在年际尺度上,除地表向上长波辐射外,CMIP6的辐射分量的集合均值较CMIP5更接近于CERES观测值,全球地表向下短波辐射的高估和大气逆辐射的低估在CMIP6中分别降低了1.9 W/m²和3.3 W/m²。除大气逆辐射外,CMIP6的辐射分量在多模式间的一致性较CMIP5提高。在北极,CMIP6对大气层顶反射短波、大气层顶出射长波和地表向下短波辐射的模拟偏差较CMIP5大。在南北纬60°,CMIP6对大气逆辐射的模拟偏差较CMIP5大。其他区域CMIP6的辐射分量更接近CERES观测值。CMIP6模拟的地表向下短波辐射和大气逆辐射的不确定性较大区域面积较CMIP5减小,但不确定性极大区域面积无变化。地表净辐射的不确定性空间分布在两代CMIP间变化甚小。青藏高原、赤道太平洋、热带雨林、阿拉伯半岛和南极洲沿海依然是地球系统模式模拟辐射收支不确定性极大的关键区域。  相似文献   

A singular evolutive extended Kalman filter to assimilate ocean color data in a coupled physical–biochemical model of the North Atlantic ocean     

V. Carmillet  J. -M. Brankart  P. Brasseur  H. Drange  G. Evensen  J. Verron 《Ocean Modelling》2001,3(3-4)

Within the European DIADEM project, a data assimilation system for coupled ocean circulation and marine ecosystem models has been implemented for the North Atlantic and the Nordic Seas. One objective of this project is to demonstrate the relevance of sophisticated methods to assimilate satellite data such as altimetry, surface temperature and ocean color, into realistic ocean models. In this paper, the singular evolutive extended Kalman (SEEK) filter, which is an advanced assimilation scheme where three-dimensional, multivariate error statistics are taken into account, is used to assimilate ocean color data into the biological component of the coupled system. The marine ecosystem model, derived from the FDM model [J. Mar. Res. 48 (1990) 591], includes 11 nitrogen and carbon compartments and describes the synthesis of organic matter in the euphotic zone, its consumption by animals of upper trophic levels, and the recycling of detritic material in the deep ocean. The circulation model coupled to the ecosystem is the Miami isopycnic coordinate ocean model (MICOM), which covers the Atlantic and the Arctic Oceans with an enhanced resolution in the North Atlantic basin. The model is forced with realistic ECMWF ocean/atmosphere fluxes, which permits to resolve the seasonal variability of the circulation and mixed layer properties. In the twin assimimation experiments reported here, the predictions of the coupled model are corrected every 10 days using pseudo-measurements of surface phytoplankton as a substitute to chlorophyll concentrations measured from space. The diagnostics of these experiments indicate that the assimilation is feasible with a reduced-order Kalman filter of small rank (of order 10) as long as a sufficiently good identification of the error structure is available. In addition, the control of non-observed quantities such as zooplankton and nitrate concentrations is made possible, owing to the multivariate nature of the analysis scheme. However, a too severe truncation of the error sub-space downgrades the propagation of surface information below the mixed layer. The reduction of the actual state vector to the surface layers is therefore investigated to improve the estimation process in the perspective of sea-viewing wide field-of-view sensor (SeaWiFS) data assimilation experiments.  相似文献